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Peptide & Protein Molecular Analysis

High-resolution mass spectrometry and molecular weight determination for peptides and small proteins. Confirm identity, detect modifications, and characterize complex mixtures with ESI-MS and MALDI-TOF.

At a Glance

What is peptide molecular analysis and what does it include?

Peptide molecular analysis uses mass spectrometry to determine the exact molecular weight of a peptide and confirm its primary sequence. At Cert Biohealth Testing Labs, we use ESI-MS and LC-MS/MS to verify identity, detect chemical modifications (oxidation, deamidation, acetylation), characterize impurities, and provide full spectral data. Standard turnaround is 9–11 business days from sample receipt.

Molecular Analysis Services

Our analytical chemists use state-of-the-art mass spectrometry platforms to characterize peptides at the molecular level, providing data suitable for research publications and regulatory submissions.

ESI-MS Identity Confirmation

Electrospray ionization mass spectrometry to confirm peptide molecular weight and primary sequence identity with high accuracy.

MALDI-TOF Analysis

Matrix-assisted laser desorption ionization for rapid molecular weight screening of peptides, proteins, and complex mixtures.

LC-MS/MS Characterization

Tandem mass spectrometry coupled with liquid chromatography for comprehensive characterization of peptide sequence and modifications.

Modification Detection

Identification of post-synthetic modifications including oxidation, deamidation, acetylation, and disulfide bond formation.

Molecular Weight Determination

Precise molecular weight measurement with sub-ppm accuracy for quality control and regulatory documentation.

Sequence Verification

De novo sequencing and sequence tag identification to verify peptide primary structure against theoretical mass.

Instrument Specifications

ESI-MS Parameters

Mass accuracy<5 ppm
Mass range200–4,000 Da (per charge)
ResolutionHigh-resolution (>20,000 FWHM)
Sample required0.5–2 mg lyophilized
Turnaround9–11 business days
Rush service2–3 business days

Report Contents

Full mass spectrum
Deconvoluted molecular weight
Theoretical vs. observed comparison
Modification annotations
Scientist signature & date
Raw instrument files on request

FAQ – Molecular Analysis

What is the difference between ESI-MS and MALDI-TOF?

ESI-MS (electrospray ionization) is best for quantitative work and LC-coupled analysis, producing multiple charge states that allow accurate molecular weight calculation. MALDI-TOF (matrix-assisted laser desorption) is faster for single-point MW screening but less quantitative. We recommend ESI-MS for regulatory-grade COA work and MALDI-TOF for rapid screening of large peptide libraries.

Can you detect chemical modifications in my peptide?

Yes. LC-MS/MS analysis can detect common modifications including oxidation (+16 Da), deamidation (+1 Da), acetylation (+42 Da), disulfide bonds, TFA adducts, and many others. We compare the observed spectrum against the theoretical mass of the target sequence and flag all discrepancies.

How much sample do I need for molecular analysis?

Typically 0.5–2 mg of lyophilized peptide. For difficult or very large peptides, we may request up to 5 mg. Contact us at info@certbiohealth.ca to discuss your specific sequence before shipping.

Can I get my raw mass spectrometry data files?

Yes. Raw instrument files (.raw, .d, mzML) are available upon request at no additional cost. These are commonly needed for research publications and grant applications.

Can you analyze cyclic peptides or peptides with unusual modifications?

Yes. We have experience with cyclic peptides, lipopeptides, PEGylated peptides, and peptides bearing non-natural amino acids. Contact us with your sequence and modification details for a custom quote.

Characterize Your Peptide at the Molecular Level

Precise molecular weight determination and sequence verification using high-resolution mass spectrometry. Results in 9–11 business days.

+1 (416) 000-0000  |  info@certbiohealth.ca

Request a Molecular Analysis Quote